New battery design from MIT could give electric vehicles a jolt
A radically new approach to the design of batteries, developed by researchers at MIT, could provide a lightweight and inexpensive alternative to existing batteries for electric vehicles and the power grid. The technology could even make “refueling” such batteries as quick and easy as pumping gas into a conventional car.
The new battery relies on an innovative architecture called a semi-solid flow cell, in which solid particles are suspended in a carrier liquid and pumped through the system. In this design, the battery’s active components—the positive and negative electrodes, or cathodes and anodes—are composed of particles suspended in a liquid electrolyte. These two different suspensions are pumped through systems separated by a filter, such as a thin porous membrane.
The work was carried out by Mihai Duduta ’10 and graduate student Bryan Ho, under the leadership of professors of materials science W. Craig Carter and Yet-Ming Chiang. It is described in a paper published May 20 in the journal Advanced Energy Materials. The paper was co-authored by visiting research scientist Pimpa Limthongkul ’02, postdoc Vanessa Wood ’10 and graduate student Victor Brunini ’08.
One important characteristic of the new design is that it separates the two functions of the battery—storing energy until it is needed, and discharging that energy when it needs to be used—into separate physical structures. (In conventional batteries, the storage and discharge both take place in the same structure.) Separating these functions means that batteries can be designed more efficiently, Chiang says.
The new design should make it possible to reduce the size and the cost of a complete battery system, including all of its structural support and connectors, to about half the current levels. That dramatic reduction could be the key to making electric vehicles fully competitive with conventional gas- or diesel-powered vehicles, the researchers say.
Another potential advantage is that in vehicle applications, such a system would permit the possibility of simply “refueling” the battery by pumping out the liquid slurry and pumping in a fresh, fully charged replacement, or by swapping out the tanks like tires at a pit stop, while still preserving the option of simply recharging the existing material when time permits.
Flow batteries have existed for some time, but have used liquids with very low energy density (the amount of energy that can be stored in a given volume). Because of this, existing flow batteries take up much more space than fuel cells and require rapid pumping of their fluid, further reducing their efficiency.
The new semi-solid flow batteries pioneered by Chiang and colleagues overcome this limitation, providing a 10-fold improvement in energy density over present liquid flow-batteries, and lower-cost manufacturing than conventional lithium-ion batteries. Because the material has such a high energy density, it does not need to be pumped rapidly to deliver its power. “It kind of oozes,” Chiang says. Because the suspensions look and flow like black goo and could end up used in place of petroleum for transportation, Carter says, “We call it ‘Cambridge crude.’”
The key insight by Chiang’s team was that it would be possible to combine the basic structure of aqueous-flow batteries with the proven chemistry of lithium-ion batteries by reducing the batteries’ solid materials to tiny particles that could be carried in a liquid suspension—similar to the way quicksand can flow like a liquid even though it consists mostly of solid particles. “We’re using two proven technologies, and putting them together,” Carter says.
In addition to potential applications in vehicles, the new battery system could be scaled up to very large sizes at low cost. This would make it particularly well-suited for large-scale electricity storage for utilities, potentially making intermittent, unpredictable sources such as wind and solar energy practical for powering the electric grid.